Chemisorption AnalysisChemical Adsorption by Static and Dynamic MethodsChemisorption,alsoknownaschemicaladsorption,concernstheformationofchemicalbondsbetweenanadsorbatespeciesandtheactivesurface ofasamplematerial.Chemisorptionisparticularlysuitedtothecharacterisationandoptimisationofcatalystsbutitcanalsobeappliedtovirtually anymetalliccontainingspeciesonaninertsupportmaterial,irrespectiveofitsapplication.Chemisorptionanalysisprovidesessentialinformation onactivemetalsurfacearea,dispersionandcrystallitesize.Essentially,thiscanbeusedtodeterminetheavailabilityoftheactivespecieswhich directlydeterminesefficiency,efficacyandcapacity.Suchinvestigationsareapplicablethroughoutaproductslife-cycle,fromthefabrication processtoinvestigatingdegradationduringuseandultimatelythesuccessofaregenerationprocess.Further,complimentary,characterisations arealsoavailableviaTemperatureProgrammedAnalysisandthemeasurementofiso-stericHeatofAdsorption,moredetailsareavailableontheir respective pages.
Key ApplicationsCharacterisation of availability of active speciesProduct formulation and process controlQC control of fabrication processesPerformance determination: efficiency and capacityAssessment of chemical activityDetermination of performance loss of time and useSuccess of re-generation processesStandard analyses using CO and H2 probe moleculesSpecialised probe molecules: N2O for Cu analysis
At MCA Services we offer two different chemisorption techniques applying a range of adsorbate options, meaning that most active metallic species can be analysed and characterised. We use state-of-the-art Micromeritics 3 Flex (TCD) and AutoChem II instruments which ensure analyses of great flexibility and precision. The static chemisorption method is undertaken at a constant analysis temperature over a range of relative adsorption pressures. Two adsorption isotherms are recorded: the first comprising chemically (strong) and physically (weak) adsorption whilst the second only comprises the weak physisorbed adsorbate. The molar volume of the chemically adsorbed probe molecule can then be determined and applied to the calculation of active metal dispersion, surface area and crystallite size. Dynamic, or pulse chemisorption is undertaken at atmospheric pressure using a flowing gas stream of an inert carrier. Successive injections of a calibrated volume of the adsorbate gas are then periodically made to the carrier gas and a Thermal Conductivity Detector is used to measure the volume of the injection not chemically adsorbed to the sample material. Analysis is complete when no further adsorbate is chemically adsorbed to the sample material. The total volume of chemically adsorbed probe molecule can the be ascertained and the same calculations of active metal dispersion, surface area and crystallite size can be made.
Analytical Options and HighlightsStatic chemisorption analysisDynamic (pulse) chemisorption analysisWide choice of analysis temperaturesChoice of adsorbate: H2, CO & N2OWide choice and flexibility of pre-reduction conditionsActive species dispersion (%)Active species surface area and total sample surface areaActive species crystallite sizeComplimentary Temperature Programmed AnalysesComplimentary Heat of Adsorption analysis
At MCA Services we have decades of experience in the analysis and characterisation of materials by chemisorption and are always happy to discuss specific samples and applications. The flexibility of our analytical options combined with our expertise ensures that the most appropriate analytical test, or combination of tests, are selected for your particular sample, application and requirements. We also provide assistance with the interpretation of results and more information about these analytical options and the background operation and theory can be found on our YouTube channel.
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MCA Services
Key ApplicationsCharacterisation of availability of active speciesProduct formulation and process controlQC control of fabrication processesPerformance determination: efficiency and capacityAssessment of chemical activityDetermination of performance loss of time and useSuccess of re-generation processesStandard analyses using CO and H2 probe moleculesSpecialised probe molecules: N2O for Cu analysis
Chemisorption AnalysisChemical Adsorption by Static and Dynamic MethodsChemisorption,alsoknownaschemicaladsorption,concernsthe formationofchemicalbondsbetweenanadsorbatespeciesand theactivesurfaceofasamplematerial.Chemisorptionis particularlysuitedtothecharacterisationandoptimisationof catalystsbutitcanalsobeappliedtovirtuallyanymetallic containingspeciesonaninertsupportmaterial,irrespectiveofits application.Chemisorptionanalysisprovidesessential informationonactivemetalsurfacearea,dispersionand crystallitesize.Essentially,thiscanbeusedtodeterminethe availabilityoftheactivespecieswhichdirectlydetermines efficiency,efficacyandcapacity.Suchinvestigationsare applicablethroughoutaproductslife-cycle,fromthefabrication processtoinvestigatingdegradationduringuseandultimately thesuccessofaregenerationprocess.Further,complimentary, characterisationsarealsoavailableviaTemperatureProgrammed AnalysisandthemeasurementofisostericHeatofAdsorption, more details are available on their respective pages.
At MCA Services we offer two different chemisorption techniques applying a range of adsorbate options, meaning that most active metallic species can be analysed and characterised. We use state-of-the-art Micromeritics 3 Flex (TCD) and AutoChem II instruments which ensure analyses of great flexibility and precision. The static chemisorption method is undertaken at a constant analysis temperature over a range of relative adsorption pressures. Two adsorption isotherms are recorded: the first comprising chemically (strong) and physically (weak) adsorption whilst the second only comprises the weak physiosorbed adsorbate. The molar volume of the chemically adsorbed probe molecule can then be determined and applied to the calculation of active metal dispersion, surface area and crystallite size. Dynamic, or pulse chemisorption is undertaken at atmospheric pressure using a flowing gas stream of an inert carrier. Successive injections of a calibrated volume of the adsorbate gas are then periodically made to the carrier gas and a Thermal Conductivity Detector is used to measure the volume of the injection not chemically adsorbed to the sample material. Analysis is complete when no further adsorbate is chemically adsorbed to the sample material. The total volume of chemically adsorbed probe molecule can the be ascertained and the same calculations of active metal dispersion, surface area and crystallite size can be made.
Analytical Options and HighlightsStatic chemisorption analysisDynamic (pulse) chemisorption analysisWide choice of analysis temperaturesChoice of adsorbate: H2, CO & N2OWide choice and flexibility of pre-reduction conditionsActive species dispersion (%)Active species surface area and total sample surface areaActive species crystallite sizeCharacterisations by Temperature Programmed AnalysisComplimentary Heat of Adsorption analysis
At MCA Services we have decades of experience in the analysis and characterisation of materials by chemisorption and are always happy to discuss specific samples and applications. The flexibility of our analytical options combined with our expertise ensures that the most appropriate analytical test, or combination of tests, are selected for your particular sample, application and requirements. We also provide assistance with the interpretation of results and more information about these analytical options and the background operation and theory can be found on our YouTube channel.