Contact Us: 01763 262333
MCA Services
Tel: 01763 262333
Chemisorption Analysis Chemical Adsorption by Static and Dynamic Methods Chemisorption, also known as chemical adsorption, concerns the formation of chemical bonds between an adsorbate species and the active surface of a sample material. Chemisorption is particularly suited to the characterisation and optimisation of catalysts but it can also be applied to virtually any metallic containing species on an inert support material, irrespective of its application. Chemisorption analysis provides essential information on active metal surface area, dispersion and crystallite size. Essentially, this can be used to determine the availability of the active species which directly determines efficiency, efficacy and capacity. Such investigations are applicable throughout a products life-cycle, from the fabrication process to investigating degradation during use and ultimately the success of a regeneration process. Further, complimentary, characterisations are also available via Temperature Programmed Analysis and the measurement of iso-steric Heat of Adsorption, more details are available on their respective pages.
Key Applications Characterisation of availability of active species Product formulation and process control QC control of fabrication processes Performance determination: efficiency and capacity Assessment of chemical activity Determination of performance loss of time and use Success of re-generation processes Standard analyses using CO and H 2 probe molecules Specialised probe molecules: N 2 O for Cu analysis
Dynamic pulse chemisorption analysis
At   MCA   Services   we   offer   two   different   chemisorption   techniques   applying   a   range   of   adsorbate   options,   meaning   that   most   active   metallic species   can   be   analysed   and   characterised.   We   use   state-of-the-art   Micromeritics   3   Flex   (TCD)   and   AutoChem   II   instruments   which   ensure analyses of great flexibility and precision. The   static   chemisorption   method   is   undertaken   at   a   constant   analysis   temperature   over   a   range   of   relative   adsorption   pressures.   Two   adsorption isotherms   are   recorded:   the   first   comprising   chemically   (strong)   and   physically   (weak)   adsorption   whilst   the   second   only   comprises   the   weak physisorbed   adsorbate.   The   molar   volume   of   the   chemically   adsorbed   probe   molecule   can   then   be   determined   and   applied   to   the   calculation   of active metal dispersion, surface area and crystallite size. Dynamic,   or   pulse   chemisorption   is   undertaken   at   atmospheric   pressure   using   a   flowing   gas   stream   of   an   inert   carrier.   Successive   injections   of   a calibrated   volume   of   the   adsorbate   gas   are   then   periodically   made   to   the   carrier   gas   and   a   Thermal   Conductivity   Detector   is   used   to   measure   the volume   of   the   injection   not   chemically   adsorbed   to   the   sample   material.   Analysis   is   complete   when   no   further   adsorbate   is   chemically   adsorbed to   the   sample   material.   The   total   volume   of   chemically   adsorbed   probe   molecule   can   the   be   ascertained   and   the   same   calculations   of   active metal dispersion, surface area and crystallite size can be made.
Analytical Options and Highlights Static chemisorption analysis Dynamic (pulse) chemisorption analysis Wide choice of analysis temperatures Choice of adsorbate: H 2 , CO & N 2 O Wide choice and flexibility of pre-reduction conditions Active species dispersion (%) Active species surface area and total sample surface area Active species crystallite size Complimentary Temperature Programmed Analyses Complimentary Heat of Adsorption analysis
Static chemisorption analysis
At   MCA   Services   we   have   decades   of   experience   in   the   analysis   and   characterisation   of   materials   by   chemisorption   and   are   always   happy   to discuss   specific   samples   and   applications.   The   flexibility   of   our   analytical   options   combined   with   our   expertise   ensures   that   the   most   appropriate analytical   test,   or   combination   of   tests,   are   selected   for   your   particular   sample,   application   and   requirements.   We   also   provide   assistance   with   the interpretation   of   results   and   more   information   about   these   analytical   options   and   the   background   operation   and   theory   can   be   found   on   our YouTube channel.
01763 262333
MCA Services
Key Applications Characterisation of availability of active species Product formulation and process control QC control of fabrication processes Performance determination: efficiency and capacity Assessment of chemical activity Determination of performance loss of time and use Success of re-generation processes Standard analyses using CO and H 2 probe molecules Specialised probe molecules: N 2 O for Cu analysis
Chemisorption Analysis Chemical Adsorption by Static and Dynamic Methods Chemisorption, also known as chemical adsorption, concerns the formation of chemical bonds between an adsorbate species and the active surface of a sample material. Chemisorption is particularly suited to the characterisation and optimisation of catalysts but it can also be applied to virtually any metallic containing species on an inert support material, irrespective of its application. Chemisorption analysis provides essential information on active metal surface area, dispersion and crystallite size. Essentially, this can be used to determine the availability of the active species which directly determines efficiency, efficacy and capacity. Such investigations are applicable throughout a products life-cycle, from the fabrication process to investigating degradation during use and ultimately the success of a regeneration process. Further, complimentary, characterisations are also available via Temperature Programmed Analysis and the measurement of isosteric Heat of Adsorption, more details are available on their respective pages.
At   MCA   Services   we   offer   two   different   chemisorption   techniques applying   a   range   of   adsorbate   options,   meaning   that   most   active metallic   species   can   be   analysed   and   characterised.   We   use   state- of-the-art     Micromeritics     3     Flex     (TCD)     and     AutoChem     II instruments    which    ensure    analyses    of    great    flexibility    and precision. The    static    chemisorption    method    is    undertaken    at    a    constant analysis     temperature     over     a     range     of     relative     adsorption pressures.    Two    adsorption    isotherms    are    recorded:    the    first comprising   chemically   (strong)   and   physically   (weak)   adsorption whilst     the     second     only     comprises     the     weak     physiosorbed adsorbate.   The   molar   volume   of   the   chemically   adsorbed   probe molecule   can   then   be   determined   and   applied   to   the   calculation   of active metal dispersion, surface area and crystallite size. Dynamic,   or   pulse   chemisorption   is   undertaken   at   atmospheric pressure   using   a   flowing   gas   stream   of   an   inert   carrier.   Successive injections   of   a   calibrated   volume   of   the   adsorbate   gas   are   then periodically   made   to   the   carrier   gas   and   a   Thermal   Conductivity Detector   is   used   to   measure   the   volume   of   the   injection   not chemically   adsorbed   to   the   sample   material.   Analysis   is   complete when   no   further   adsorbate   is   chemically   adsorbed   to   the   sample material.   The   total   volume   of   chemically   adsorbed   probe   molecule can   the   be   ascertained   and   the   same   calculations   of   active   metal dispersion, surface area and crystallite size can be made.
Analytical Options and Highlights Static chemisorption analysis Dynamic (pulse) chemisorption analysis Wide choice of analysis temperatures Choice of adsorbate: H 2 , CO & N 2 O Wide choice and flexibility of pre-reduction conditions Active species dispersion (%) Active species surface area and total sample surface area Active species crystallite size Characterisations by Temperature Programmed Analysis Compli mentary Heat of Adsorption analysis
Static chemisorption anlaysis
At   MCA   Services   we   have   decades   of   experience   in   the   analysis and    characterisation    of    materials    by    chemisorption    and    are always   happy   to   discuss   specific   samples   and   applications.   The flexibility   of   our   analytical   options   combined   with   our   expertise ensures   that   the   most   appropriate   analytical   test,   or   combination of   tests,   are   selected   for   your   particular   sample,   application   and requirements.   We   also   provide   assistance   with   the   interpretation of   results   and   more   information   about   these   analytical   options and   the   background   operation   and   theory   can   be   found   on   our YouTube channel.
chemisorption by static volumetric carbon monoxide sorption