Expertise in the Physical Characterisation of Materials
01763 262333
MCA Services Unit 1A Long Barn, North End, Meldreth, Cambridgeshire SG8 6NT UK
01763 262333
© MCA Services
Chemisorption Analysis (Chemical Adsorption) Static Chemisorption Dynamic (Pulse) Chemisorption CO, H2 and O2 Chemisorption Options Chemical   adsorption,   or   chemisorption   analysis,   concerns   the   formation   of   chemical   bonds   between   an   adsorptive   gas   and   the   active   surface sites   on   a   sample.   Chemisorption   is   particularly   suited   to   the   characterisation   and   optimisation   of   catalysts.   Chemisorption   is   used   to determine   the   surface   area,   dispersion   and   crystallite   size   of   active   metals   in   a   catalyst.   These   essentially   provide   critical   information   regarding the   surface   chemistry   of   a   sample   and   the   availability   of   the   catalytically-active   constituents.   With   this   information   it   is   possible   to   assess   the efficiency    of    a    catalyst    sample    for    a    given    chemical    reaction,    which    is    critical    to    the    development    of    catalytic    materials.    Alternatively, chemisorption can be applied to functioning catalysts in order to monitor degradation over time and assess the success of re-generation. Key Information. Static chemisorption analysis Dynamic (pulse) analysis Choice of analysis temperature Choice of in-situ pre-reduction conditions Carbon monoxide chemisorption Hydrogen chemisorption Oxygen chemisorption Other probe gases available in request Metal dispersion (%) Metallic (active) surface area of metal Metallic (active) surface area of sample Crystallite size (nm) At   MCA   Services   we   offer   two   different   chemisorption   techniques,   both   using   the   state-of-the-art   Micromeritics   3Flex   TCD   Chemisorption instrument. Static   chemisorption   is   undertaken   at   a   constant   temperature   over   a   range   of   relative   pressures   with   two   adsorption   isotherms   being measured.   The   first   isotherm   is   due   to   both   chemically   (strong)   and   physically   (weak)   adsorbed   species   whereas   the   second   isotherm   is   due solely   to   physisorbed   species.   The   volume   chemically   adsorbed   onto   the   sample   can   then   be   determined   and   applied   to   calculation   of   active metal area, dispersion, etc.  Dynamic,   or   pulse   chemisorption,   is   undertaken   at   atmospheric   pressure   using   a   flowing   gas   technique.   Successive   injections   of   a   calibrated volume   of   adsorptive   gas   are   made   to   the   sample   and   a   TCD   (Thermal   Conductivity   Detector)   is   used   to   measure   the   volume   of   adsorptive   gas which   is   not   chemisorbed   onto   the   sample.   The   sample   is   saturated   with   adsorptive   gas   when   a   complete   injection   is   passed   through   to   the TCD, the volume of adsorptive chemisorbed can then be calculated and applied the to calculation of active metal area, dispersion, etc. Alternative   chemisorption   analyses   include   a   range   of   temperature   programmed   techniques,   such   as   TPD,   TPR   and   TPD,   please   see   our Temperature Programmed Analyses page for more details. 
co chemical adsorption - chemisorption - isotherms dynamic / pulse hydrogen chemisorption
Expertise in the Physical Characterisation of Materials
MCA Services Unit 1A Long Barn, North End, Meldreth, Cambridgeshire SG8 6NT UK
01763 262333
© MCA Services
Chemisorption Analysis (Chemical Adsorption) Static Chemisorption Dynamic (Pulse) Chemisorption CO, H2 and O2 Chemisorption Options Chemical   adsorption,   or   chemisorption   analysis,   concerns   the   formation of   chemical   bonds   between   an   adsorptive   gas   and   the   active   surface sites     on     a     sample.     Chemisorption     is     particularly     suited     to     the characterisation   and   optimisation   of   catalysts.   Chemisorption   is   used   to determine    the    surface    area,    dispersion    and    crystallite    size    of    active metals    in    a    catalyst.    These    essentially    provide    critical    information regarding   the   surface   chemistry   of   a   sample   and   the   availability   of   the catalytically-active   constituents.   With   this   information   it   is   possible   to assess   the   efficiency   of   a   catalyst   sample   for   a   given   chemical   reaction, which   is   critical   to   the   development   of   catalytic   materials.   Alternatively, chemisorption    can    be    applied    to    functioning    catalysts    in    order    to monitor degradation over time and assess the success of re-generation. Key Information. Static chemisorption analysis Dynamic (pulse) analysis Choice of analysis temperature Choice of in-situ pre-reduction conditions Carbon monoxide chemisorption Hydrogen chemisorption Oxygen chemisorption Other probe gases available in request Metal dispersion (%) Metallic (active) surface area of metal Metallic (active) surface area of sample Crystallite size (nm) At   MCA   Services   we   offer   two   different   chemisorption   techniques,   both using     the     state-of-the-art     Micromeritics     3Flex     TCD     Chemisorption instrument. Static   chemisorption   is   undertaken   at   a   constant   temperature   over   a range     of     relative     pressures     with     two     adsorption     isotherms     being measured.    The    first    isotherm    is    due    to    both    chemically    (strong)    and physically   (weak)   adsorbed   species   whereas   the   second   isotherm   is   due solely   to   physisorbed   species.   The   volume   chemically   adsorbed   onto   the sample    can    then    be    determined    and    applied    to    calculation    of    active metal area, dispersion, etc.  Dynamic,   or   pulse   chemisorption,   is   undertaken   at   atmospheric   pressure using    a    flowing    gas    technique.    Successive    injections    of    a    calibrated volume   of   adsorptive   gas   are   made   to   the   sample   and   a   TCD   (Thermal Conductivity   Detector)   is   used   to   measure   the   volume   of   adsorptive   gas which   is   not   chemisorbed   onto   the   sample.   The   sample   is   saturated   with adsorptive   gas   when   a   complete   injection   is   passed   through   to   the   TCD, the    volume    of    adsorptive    chemisorbed    can    then    be    calculated    and applied the to calculation of active metal area, dispersion, etc. Alternative    chemisorption    analyses    include    a    range    of    temperature programmed    techniques,    such    as    TPD,    TPR    and    TPD,    please    see    our Temperature Programmed Analyses page for more details. 
Dynamic pulse hydrogen chemisorption
01763262333
static co chemisorption by isotherm method